International Journal of Modern Science and Technology

INDEXED IN 

​​​​​​​April 2019, Vol. 4, No. 4, pp 79-91. 

​​Cationic Modification of Cotton for Salt-free Reactive Dyeing: A Review

Asaye Dessie Wolela*
Department of Textile Engineering, Kombolcha Institute of Technology, Wollo University, Kombolcha, Ethiopia.

​​*Corresponding author’s e-mail: ase25dessie@gmail.com

Abstract

Cotton is still the king of fibres, and most of world’s apparel is made of cotton due to its unique comfort, good dyeability, ease of production, biodegradability, and relatively low cost. To satisfy consumers aesthetically, cotton products, like garments and household textiles, must have a large color gamut and satisfactory fastness. The most popular dyes for dyeing cotton are the reactive dyes because of their brightness of shade, wide colour gamut, flexible application procedures and all-round good colour fastness properties of the resultant dyeing’s. In recent years, reactive dyes maintain the largest annual consumption in the world among the dyes used for cotton dyeing. But some problems, such as low dye utilization, large amount of electrolyte used and high volume of wastewater discharged, always exist in the application of reactive dyes. With growing popularity of reactive dyes for dyeing of cotton, environmental problems associated with their use have received attention. Cotton acquires negative charge in aqueous medium and thus repels negatively charged dye anion during dyeing. Such repulsion between fibre and dye is offset by using large quantity of salt in dye bath, particularly for reactive dyes. A low dye bath exhaustion also leads to low dye fixation of reactive dyes on cotton. Thus, the use of high salt concentration and low reactive dye fixation lead to environmental problems related to highly coloured effluent with high salt content. Hence, modifying the cotton fibre to increase dye-fibre interaction is therefore the best route to overcome the lack of affinity for cotton to reactive dyes making salt-free reactive dyeing. However, majority of the chemicals used for imparting cationic sites in cotton are themselves not ecofriendly.

Keywords: Cotton; Cationization; Cationic agents; Salt Free Dyeing; Reactive dyes.

References

  1. Burkinshaw S, Kabambe O. Attempts to reduce water and chemical usage in the removal of bifunctional reactive dyes from cotton: Part 2 bis (vinyl sulfone), aminochlorotriazine/vinyl sulfone and bis (aminochlorotriazine/vinyl sulfone) dyes. Dyes Pigm 2011;88:220-9.
  2. Petrinić, Curlin IM. Textile wastewater treatment with membrane bioreactor and water re-use. Tekstil: Journal of Textile and Clothing Technology 2009;58:11-9.
  3. Ma W, Zhang SF, Yang JZ. Development of functional polymers in modification of cotton for improving dyeability of reactive dyes.  The Proceedings of the 3rd international conference on functional molecules, 2002. Citeseer.
  4. Chattopadhyay D. Cationization of cotton for low-salt or salt-free dyeing. Indian Journal of Fibre and Textile Research 2001;26:108-15
  5. Chattopadhyay D, Chavan, R, Sharma J. Salt-free reactive dyeing of cotton. International Journal of Clothing Science and Technology 2007;19:99-108.
  6. Fu S, Hinks D, Hauser P, Ankeny M. High efficiency ultra-deep dyeing of cotton via mercerization and cationization. Cellulose 2013;20:3101-10.
  7. Montazer M, Malek R, Rahimi A. Salt free reactive dyeing of cationized cotton. Fibers and Polymers 2007;8:608-12.
  8. Tutak M, Oktay Özdemir A. Reactive dyeing of cationized cotton: effects on the dyeing yield and the fastness properties. Journal of Applied Polymer Science 2011;119:500-4.
  9. Allegre C, Moulin P, Maisseu M, Charbit F. Treatment and reuse of reactive dyeing effluents. Journal of Membrane Science 2006;269:15-34.
  10. Singha K, Maity S, Singha M. The salt-free dyeing on cotton: an approach to effluent free mechanism; can chitosan be a potential option?. International Journal of Textile Science 2012;1:69-77.
  11. Ramasamy M, Kandasaamy P. Effect of cationization of cotton on it's dyeability. Indian Journal of Fibre and Textile Research 2005;30:15-233.
  12. Kannan MSS, Gobalakrishnan M, Kumaravel S, Nithyanadan R, Rajashankar K, Vadicherala T. Influence of cationization of cotton on reactive dyeing. Textile and Apparel Technology and Management 2006;5:23-30.
  13. Fu S. Studies on dyeing cationized cotton, Ph.D Thesis. North Carolina State University. 2016.
  14. Farrell MJ. Sustainable Cotton Dyeing. Ph.D Thesis. North Carolina State University. 2011.
  15. Periyasamy AP, Dhurai B, Thangamani K. Salt-free dyeing–a new method of dyeing on lyocell/cotton blended fabrics with reactive dyes. Autex Res J 2011;11:14-17.
  16. Shahin M. The influence of cationization on the dyeing performance of cotton fabrics with direct dyes. International Journal of Engineering Research and Applications 2015;5:62-70.
  17. Sharma R, Sayed U. Surface Modification of Cellulosic Fabric. International Journal of Advances in Chemical Engineering and Biological Sciences 2016;3:90-6.
  18. Ristić N, Ristić I. Cationic Modification of Cotton Fabrics and Reactive Dyeing Characteristics. Journal of Engineered Fabrics and Fibers 2012;7:113-21.
  19. Lewis DM, Vo LT. Dyeing cotton with reactive dyes under neutral conditions. Coloration Technology 2007;123:306-11.
  20. Broadbent AD. Basic principles of textile coloration. Society of Dyers and Colourists. Bradford, West Yorkshire BD1 2JB, England. 2001.
  21. Bhuiyan MR, Shaid A, Khan M. Cationization of cotton fiber by chitosan and its dyeing with reactive dye without salt. Chemical and Materials Engineering. 2014;2:96-100.
  22. Wang Z, Xue M, Huang K, Liu Z. Textile dyeing wastewater treatment. Advances in treating textile effluent. Intech Open Limited. London, SE1 9SG, United Kingdom. 2011.
  23. Talukder ME, Kamruzzaman M, Majumder M, Rony MSH, Hossain M, Das S. Effects of Salt Concentration on the Dyeing of Various Cotton Fabrics with Reactive Dyes. International Journal of Textile Science 2017;6:7-14.
  24. Chavan RV. Environment-friendly dyeing process for cotton. Indian Journal of Fibre and Textile Research 2001;26:93-100.
  25. Moore SB, Ausley LW. Systems thinking and green chemistry in the textile industry: concepts, technologies and benefits. Journal of Cleaner Production 2004;12(6), 585-601.
  26. Taylor J. Recent developments in reactive dyes.Review of Progress in Coloration and Related Topics 2000;30(1):93-108.
  27. Lewis DM. Developments in the chemistry of reactive dyes and their application processes. Coloration Technology 2014;130(6):382-412.
  28. He WD, Broadbent PJ, Lewis DM. Reactive dye compounds. Patent WO2002096995 (Procter & Gamble). 2002.
  29. Smith B, Berger R, Freeman HS. High affinity, high efficiency fibre-reactive dyes. Coloration Technology  2006;122(4): 187-93.
  30. Morris KF, Lewis DM, Broadbent PJ. Design and application of a multifunctional reactive dye capable of high fixation efficiency on cellulose. Coloration Technology 2008;124(3):186-94.
  31. Renfrew AHM. Reactive dyes for textile fibres. Society of Dyers and Colourists. Society of Dyers and Colourists. Bradford, West Yorkshire BD1 2JB, England. 1999.
  32. Morimura N, Ojima M. New reactive dyes fixable at neutral pH. American Dyestuff Reporter 1985;74:28-36.
  33. Lewis DM, Broadbent PJ, Vo LTT. Covalent fixation of reactive dyes on cotton under neutral conditions. AATCC Review 2008;8(1):35-41.
  34. Gillingham EL, Lewis DM, Nabi A, Srikulkit K. Triazinylamino-alkylphosphonate reactive dyes for cellulosic fibres. Coloration Technology 2007;123(3):178-83.
  35. Hinks D, Burkinshaw SM, Lewis DM, Renfrew AHM. Cationic fiber reactive dyes for cellulosic fibers. AATCC Review 2001;1(5):43-6.
  36. Srikulkit K, Santifuengkul P. Salt-free dyeing of cotton cellulose with a model cationic reactive dye. Coloration Technology 2000;116(12):398-402.
  37. Zheng C, Yuan A, Wang H, Sun J. Dyeing properties of novel electrolyte-free reactive dyes on cotton fibre. Coloration Technology 2012;128(3):204-7.
  38. Rupp J. Recent developments in dyeing. Textile World 2010;160(2):36-7.
  39. European IPPC Bureau. Reference document on best available techniques for the textiles industry. Institute for Prospective Technological Studies. Spain. 2003.  
  40. Leube H, Rüttiger W, Kühnel G, et al. Textile dyeing.Ullmann’s Encyclopedia of Industrial Chemistry. Wiley-VCH Verlag GmbH & Co. KGaA; 2000.. doi:10.1002/14356007.a26_351.
  41.  Wilbers L, Seiler G. New concept for dyeing of cellulosic substrates at ultra low liquor ratios. Melliand International 2002;8(1):66-7.
  42. Khatri A, Peerzada MH, Mohsin M, White M. A review on developments in dyeing cotton fabrics with reactive dyes for reducing effluent pollution. Journal of Cleaner Production 2015;87:50-7.
  43. Ali S, Khatri Z, Brohi K. Econtrol dyeing process: an ecological and economical approach. Energy, Environment and Sustainable Development Springer. Vienna. 2012. pp. 291–297. doi:10.1007/978-3-7091-0109-4_28.
  44. Thakore KA. Application of ultrasonics in dyeing of cotton fabrics with direct dyes: Part I–Kinetics of dyeing. Indian Journal of Textile Research 1988;13:133.
  45. Thakore KA. Application of ultrasonics in dyeing of cotton fabrics with direct dyes: Part II–Diffusion kinetics. Indian Journal of Textile Research 1988;13:208.
  46. Thakore KA. Ultrasound treatment in exhaust and pad-batch dyeing. AATCC Review 2011;11(4):66-74.
  47.  Khatri Z, Memon MH, Khatri A, Tanwari A. Cold pad-batch dyeing method for cotton fabric dyeing with reactive dyes using ultrasonic energy. Ultrasonics Sonochemistry 2011;18(6):1301-7.
  48. Öner E, Başer I, Acar K. Use of ultrasonic energy in reactive dyeing of cellulosic fabrics. Journal of the Society of Dyers and Colourists 1995;111(9):279-81.
  49. Haggag K, Elshemy NS, Nasef NA. Enhancement of cotton and cotton/wool blend dyeability by microwave heating. Research Journal of Textile and Apparel 2012;16(1):34.
  50. Hashem M, Taleb MA, Haggag K. New prospects in pretreatment of cotton fabrics using microwave heating. Carbohydrate Polymers 2014;103:385-91.
  51. Schmidt A, Bach E, Schoomeyer E. The dyeing of natural fibres with reactive disperse dyes in supercritical carbon dioxide. Dyes and Pigments 2003;56(1):27-35.
  52. Özcan S, Clifford, Bartle KD, Broadbent, PJ, Lewis DM. Dyeing of modified cotton fibres with disperse dyes from supercritical carbon dioxide. Journal of the Society of Dyers and Colourists 1998;114:169-73.
  53. Özcan S, Clifford, Bartle KD, Lewis DM. Dyeing of cotton fibres with disperse dyes in supercritical carbon dioxide. Dyes and Pigments 1998;36(2):103-10.
  54. Hauser PJ, Tabba AH. Improving the environmental and economic aspects of cotton dyeing using a cationised cotton. Coloration Technology 2001;117(5):282-88.
  55. Shahidi S, Wiener J, Ghoranneviss M. Surface modification methods for improving the dyeability of textile fabrics. Eco-Friendly Textile Dyeing and Finishing. Intech Open Limited. London, SE1 9SG, United Kingdom. 2013.
  56. Tseghai GB, Makokha LW. Surface Modification of cotton using slaughterhouse wastes. International Journal of Fashion and Textile Engineering 2015;9:3011-15.
  57. Schlack P. Manufacture of organic compounds containing basic substituents. US Patent: 2131120. 1938.
  58. Champetier G, Montegudet G, Petit J. Obtention De Derives Amines De La Cellulose. Comptes Rendus Hebdomadaires Des Seances De L Academie Des Sciences 1955;240(19):1896-8.
  59. Merle Y. Sur La Preparation De Derives Amines De Lalcool Polyvinylique Et De Lamidon. Comptes Rendus Hebdomadaires Des Seances De L Academie Des Sciences. 1958;246(9):1425-6.
  60. Rupen M. Textile Chemists and Colorists. 1976:139.
  61. Rupin M, Veaute G, Balland J. Utilisation de composes reactifs epoxy ammonium quatinairs dans la cellulose encolorante direct et reactifs. Textilveredlung. 1970;5:829-38.
  62. Earl RH, Saunders RH, Kandles RL. Appl Poly Symp 1971;18:707.
  63. Wu TS, Chen KM. New cationic agents for improving the dyeability of cellulose fibres. I. Pretreating cotton with polyepichlorohydrinamine polymers for improving dyeability with direct dyes. Journal of the Society of Dyers and Colorists 1992;108:388-94.
  64. Wu TS, Chen KM. New cationic agents for improving the dyeability of cellulose fibres. part 2-pretreating cotton with polyepichlorohydrin-amine polymers for improving dyeability 93 with reactive dyes. Journal of the Society of Dyers and Colourists 1993;109(4):153-8.
  65. El-kharadly EA, Shakra S, Youssef BM & Youssef YA. Dyeing of chemically modified cotton fabric. Indian J Fiber Text Res 1996;21:35-40.
  66. Aktek T, Millat AM. Salt Free Dyeing of Cotton Fiber-A Critical Review. International Journal of Textile Science 2017;6:21-33.
  67. Lewis DM, Lei X. Improved cellulose dyeability by chemical modification of the fiber. Journal of the Society of Dyers and Colourists 1989;21(10):23-9.

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